Comparison of three-dimensional and two-dimensional statistical mechanics of shear layers for flow between two parallel plates

It is shown that the averaged velocity profiles predicted by statistical mechanics of point vortices and statistical mechanics of vortex lines are practically indistinguishable for a shear flow between two parallel walls

Interaction of a vortex ring with the free surface of ideal fluid

The interaction of a small vortex ring with the free surface of a perfect fluid is considered. In the frame of the point ring approximation the asymptotic expression for the Fourier-components of radiated surface waves is obtained in the case when the vortex ring comes from infinity and has both horizontal and vertical components of the velocity. The non-conservative corrections to the equations of motion of the ring, due to Cherenkov radiation, are derived.Comment: LaTeX, 15 pages, 1 eps figur

The microcanonical thermodynamics of finite systems: The microscopic origin of condensation and phase separations; and the conditions for heat flow from lower to higher temperatures

Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical mechanics especially its key quantity, entropy. Whereas in conventional thermostatistics, the homogeneity and extensivity of the system and the concavity of its entropy are central conditions, these fail for the systems considered here. For example, at phase separation, the entropy, S(E), is necessarily convex to make exp[S(E)-E/T] bimodal in E. Particularly, as inhomogeneities and surface effects cannot be scaled away, one must be careful with the standard arguments of splitting a system into two subsystems, or bringing two systems into thermal contact with energy or particle exchange. Not only the volume part of the entropy must be considered. As will be shown here, when removing constraints in regions of a negative heat capacity, the system may even relax under a flow of heat (energy) against a temperature slope. Thus the Clausius formulation of the second law: ``Heat always flows from hot to cold'', can be violated. Temperature is not a necessary or fundamental control parameter of thermostatistics. However, the second law is still satisfied and the total Boltzmann entropy increases. In the final sections of this paper, the general microscopic mechanism leading to condensation and to the convexity of the microcanonical entropy at phase separation is sketched. Also the microscopic conditions for the existence (or non-existence) of a critical end-point of the phase-separation are discussed. This is explained for the liquid-gas and the solid-liquid transition.Comment: 23 pages, 2 figures, Accepted for publication in the Journal of Chemical Physic

Integrability and strong normal forms for non-autonomous systems in a neighbourhood of an equilibrium

The paper deals with the problem of existence of a convergent "strong" normal form in the neighbourhood of an equilibrium, for a finite dimensional system of differential equations with analytic and time-dependent non-linear term. The problem can be solved either under some non-resonance hypotheses on the spectrum of the linear part or if the non-linear term is assumed to be (slowly) decaying in time. This paper "completes" a pioneering work of Pustil'nikov in which, despite under weaker non-resonance hypotheses, the nonlinearity is required to be asymptotically autonomous. The result is obtained as a consequence of the existence of a strong normal form for a suitable class of real-analytic Hamiltonians with non-autonomous perturbations.Comment: 10 page

Interplay between bending and stretching in carbon nanoribbons

We investigate the bending properties of carbon nanoribbons by combining continuum elasticity theory and tight-binding atomistic simulations. First, we develop a complete analysis of a given bended configuration through continuum mechanics. Then, we provide by tight-binding calculations the value of the bending rigidity in good agreement with recent literature. We discuss the emergence of a stretching field induced by the full atomic-scale relaxation of the nanoribbon architecture. We further prove that such an in-plane strain field can be decomposed into a first contribution due to the actual bending of the sheet and a second one due to edge effects.Comment: 5 pages, 6 figure

On a new definition of quantum entropy

It is proved here that, as a consequence of the unitary quantum evolution, the expectation value of a properly defined quantum entropy operator (as opposed to the non-evolving von Neumann entropy) can only increase during non adiabatic transformations and remains constant during adiabatic ones. Thus Clausius formulation of the second law is established as a theorem in quantum mechanics, in a way that is equivalent to the previously established formulation in terms of minimal work principle [A. E. Allahverdyan and T. M. Nieuwenhuizen, Phys. Rev. E 71, 046107 (2005)]. The corresponding Quantum Mechanical Principle of Entropy Increase is then illustrated with an exactly solvable example, namely the driven harmonic oscillator. Attention is paid to both microcanonical and canonical initial condition. The results are compared to their classical counterparts.Comment: 4 pages, 3 figure

Derivation of Boltzmann Principle

We present a derivation of Boltzmann principle $S_{B}=k_{B}\ln \mathcal{W}$ based on classical mechanical models of thermodynamics. The argument is based on the heat theorem and can be traced back to the second half of the nineteenth century with the works of Helmholtz and Boltzmann. Despite its simplicity, this argument has remained almost unknown. We present it in a modern, self-contained and accessible form. The approach constitutes an important link between classical mechanics and statistical mechanics

Relation between Stochastic Resonance and Synchronization of Passages in a Double-Well System

We calculate, numerically, the residence times (and their distribution) of a Brownian particle in a two-well system under the action of a periodic, saw-tooth type, external field. We define hysteresis in the system. The hysteresis loop area is shown to be a good measure of synchronization of passages from one well to the other. We establish connection between this stochastic synchronization and stochastic resonance in the system.Comment: To appear in PRE May 1997, figures available on reques

Minimal Work Principle and its Limits for Classical Systems

The minimal work principle asserts that work done on a thermally isolated equilibrium system, is minimal for the slowest (adiabatic) realization of a given process. This principle, one of the formulations of the second law, is operationally well-defined for any finite (few particle) Hamiltonian system. Within classical Hamiltonian mechanics, we show that the principle is valid for a system of which the observable of work is an ergodic function. For non-ergodic systems the principle may or may not hold, depending on additional conditions. Examples displaying the limits of the principle are presented and their direct experimental realizations are discussed.Comment: 4 + epsilon pages, 1 figure, revte

Does the Boltzmann principle need a dynamical correction?

In an attempt to derive thermodynamics from classical mechanics, an approximate expression for the equilibrium temperature of a finite system has been derived [M. Bianucci, R. Mannella, B. J. West, and P. Grigolini, Phys. Rev. E 51, 3002 (1995)] which differs from the one that follows from the Boltzmann principle S = k log (Omega(E)) via the thermodynamic relation 1/T= dS/dE by additional terms of "dynamical" character, which are argued to correct and generalize the Boltzmann principle for small systems (here Omega(E) is the area of the constant-energy surface). In the present work, the underlying definition of temperature in the Fokker-Planck formalism of Bianucci et al. is investigated and shown to coincide with an approximate form of the equipartition temperature. Its exact form, however, is strictly related to the "volume" entropy S = k log (Phi(E)) via the thermodynamic relation above for systems of any number of degrees of freedom (Phi(E) is the phase space volume enclosed by the constant-energy surface). This observation explains and clarifies the numerical results of Bianucci et al. and shows that a dynamical correction for either the temperature or the entropy is unnecessary, at least within the class of systems considered by those authors. Explicit analytical and numerical results for a particle coupled to a small chain (N~10) of quartic oscillators are also provided to further illustrate these facts.Comment: REVTeX 4, 10 pages, 2 figures. Accepted to J. Stat. Phy